Search for: All records

Abstract We present the Local GroupL-Band Survey, a Karl G. Jansky Very Large Array (VLA) survey producing the highest-quality 21 cm and 1–2 GHz radio continuum images to date, for the six VLA-accessible, star-forming, Local Group galaxies. Leveraging the VLA’s spectral multiplexing power, we simultaneously survey the 21 cm line at high 0.4 km s⁻¹velocity resolution, the 1–2 GHz polarized continuum, and four OH lines. For the massive spiral M31, the dwarf spiral M33, and the dwarf irregular galaxies NGC 6822, IC 10, IC 1613, and the Wolf–Lundmark–Melotte Galaxy, we use all four VLA configurations and the Green Bank Telescope to reach angular resolutions of <5″ (10–20 pc) for the 21 cm line with <10²⁰cm⁻²column density sensitivity, and even sharper views (<2″; 5–10 pc) of the continuum. Targeting these nearby galaxies (D ≲ 1 Mpc) reveals a sharp, resolved view of the atomic gas, including 21 cm absorption, and continuum emission from supernova remnants and Hiiregions. These data sets can be used to test theories of the abundance and formation of cold clouds, the driving and dissipation of interstellar turbulence, and the impact of feedback from massive stars and supernovae. Here, we describe the survey design and execution, scientific motivation, data processing, and quality assurance. We provide a first look at and publicly release the wide-field 21 cm Hidata products for M31, M33, and four dwarf irregular targets in the survey, which represent some of the highest-physical-resolution 21 cm observations of any external galaxies beyond the LMC and SMC. 

Icosahedral colloidal clusters are a new class of spherical colloidal crystals. This cluster allows for potentially superior optical properties in comparison to conventional onion-like colloidal supraballs because of the quasi-crystal structure. However, the characterization of the cluster as an optical material has until now not been achieved. Here we successfully produce icosahedral clusters by assembling silica particles using bulk water-in-oil emulsion droplets and systematically characterize their optical properties. We exploit a water-saturated oil phase to control droplet drying, thereby preparing clusters at room temperature. In comparison to conventional onion-like supraballs with a similar size, the icosahedral clusters exhibit relatively strong structural colors with weak nonresonant scattering. Simulations prove that the crystalline array inside the icosahedral cluster strengthens the collective specular diffraction. To further improve color saturation, the silica particles constituting the cluster are coated with a thin-film carbon shell. The carbon shell acts as a broad-band absorber and reduces incoherent scattering with long optical paths, resulting in vibrant blue, green, and red colors comparable to inorganic chemical pigments. 

Asymmetric vesicles are membranes in which amphiphiles are asymmetrically distributed between each membrane leaflet. This asymmetry dictates chemical and physical properties of these vesicles, enabling their use as more realistic models of biological cell membranes, which also are asymmetric, and improves their potential for drug delivery and cosmetic applications. However, their fabrication is difficult as the self-assembly of amphiphiles always leads to symmetric vesicles. Here, we report the use of water-in-oil-in-oil-in-water triple emulsion drops to direct the assembly of the two leaflets to form asymmetric vesicles. Different compositions of amphiphiles are dissolved in each of the two oil shells of the triple emulsion; the amphiphiles diffuse to the interfaces and adsorb differentially at each of the two oil/water interfaces of the triple emulsion. These middle oil phases dewet from the innermost water cores of the triple emulsion drops, leading to the formation of membranes with degrees of asymmetry up to 70%. The triple emulsion drops are fabricated using capillary microfluidics, enabling production of highly monodisperse drops at rates as high as 300 Hz. Vesicles produced by this method can very efficiently encapsulate many different ingredients; this further enhances the utility of asymmetric vesicles as artificial cells, bioreactors and delivery vehicles. 

Abstract A great proportion of molecular crystals can be made to grow as twisted fibrils. Typically, this requires high crystallization driving forces that lead to spherulitic textures. Here, it is shown how micron size channels fabricated from poly(dimethylsiloxane) (PDMS) serve to collimate the circular polycrystalline growth fronts of optically banded spherulites of twisted crystals of three compounds, coumarin, 2,5‐bis(3‐dodecyl‐2‐thienyl)‐thiazolo[5,4‐d]thiazole, and tetrathiafulvalene. The relationships between helicoidal pitch, growth front coherence, and channel width are measured. As channels spill into open spaces, collimated crystals “diffract” via small angle branching. On the other hand, crystals grown together from separate channels whose bands are out of phase ultimately become a single in‐phase bundle of fibrils by a cooperative mechanism yet unknown. The isolation of a single twist sense in individual channels is described. We forecast that such chiral molecular crystalline channels may function as chiral optical wave guides.